In the last twenty years, research activity around the environmental applications of metal–organic frameworks has bloomed due to their CO₂ capture ability, tunable properties, porosity, and well-defined crystalline structure. Thus, hundreds of MOFs have been developed. However, the impact of their production on the environment has not been investigated as thoroughly as their potential applications. In this work, the environmental performance of various synthetic routes of MOF nanoparticles, in particular ZIF-8, is assessed through a life cycle assessment. For this purpose, five representative synthesis routes were considered, and synthesis data were obtained based on available literature. The synthesis included different solvents (de-ionized water, methanol, dimethylformamide) as well as different synthetic steps (i.e., hours of drying, stirring, precursor). The findings revealed that the main environmental weak points identified during production were: (a) the use of dimethylformamide (DMF) and methanol (MeOH) as substances impacting environmental sustainability, which accounted for more than 85% of the overall environmental impacts in those synthetic routes where they were utilized as solvents and as cleaning agents at the same time; (b) the electricity consumption, especially due to the Greek energy mix which is fossil-fuel dependent, and accounted for up to 13% of the overall environmental impacts in some synthetic routes. Nonetheless, for the optimization of the impacts provided by the energy use, suggestions are made based on the use of alternative, cleaner renewable energy sources, which (for the case of wind energy) will decrease the impacts by up to 2%.

In the 21st century, sustainable development is high on the international agenda, with the implementation of green walls contributing significantly to achieving environmental and social benefits, mainly in the frame of sustainable improvement of the building sector. The installation of a greening system can provide engineered solutions for stormwater management and climate change mitigation at both the urban and building level. This facilitates improving indoor comfort conditions and reducing energy needs. In order to improve the features of products and to facilitate the implementation of a proper technical standard, this paper proposes a critical bibliographic analysis of more recent scientific works. Moreover, by means of a numerical model of an existing single-family apartment, placed in the Mediterranean climate zone, a building envelope refurbishment with a living wall is carried out. A parametric analysis provides evidence for the application of different plants’ types and insulation materials. The results are analyzed considering the energy needs, the thermo-hygrometric comfort, and the outdoor surface temperature variation of the building envelope, emphasizing that a multi-criteria design approach is needed for green vertical systems. The paper provides data and an approach useful for designers and researchers in the evaluation and optimization of the performance of greening systems.

Several parameters, including specific surface area, morphology, crystal size, and dopant concentration, play a significant role in improving the photocatalytic performance of ZnO. However, it is still unclear which of these parameters play a significant role in enhancing the photocatalytic activity. Herein, undoped and Mn-, Co-, and Cu-doped platelet-like zinc oxide (ZnO) nanostructures were synthesized via a facile microwave synthetic route, and their ultraviolet (UV) and visible-light-induced photocatalytic activities, by monitoring the gaseous acetaldehyde (CH₃CHO) degradation, were systematically investigated. Both the pure and doped ZnO nanostructures were found to be UV-active, as the CH₃CHO oxidation photocatalysts with the Cu-doped ZnO one being the most UV-efficient photocatalyst. However, upon visible light exposure, all ZnO-nanostructured samples displayed no photocatalytic activity except the Co-doped ZnO, which showed a measurable photocatalytic activity. The latter suggests that Co-doped ZnO nanostructures are potent candidates for several indoor photocatalytic applications. Various complementary techniques were utilized to improve the understanding of the influence of Mn-/Co-/Cu-doping on the photocatalytic performance of the ZnO nanostructures. Results showed that the synergetic effects of variation in morphology, surface defects, that is, V_O, high specific surface areas, and porosity played a significant role in modulating the photocatalytic activity of ZnO nanostructures.

Building materials, due to their mass and energy-consuming production processes, drastically increase the embodied energy of construction. This study assesses circularity processes for the construction industry with a life cycle assessment (LCA) of a case study located in a large cosmopolitan city. The research concludes that a significant decrease in environmental impacts results from a shift to recycled materials in the construction phase, as well as from changing the landfill disposal method to recycling. In particular, it was found that the use of recycled building materials (such as recycled cement, metal, concrete, or glass) during the construction phase and recycling disposal methods lead to an overall decrease of impact up to 65%. This work also underlines the importance of circularity in renewable energy production systems. In both wind and solar systems, most of the environmental impact caused during the production phase are paid back during the second year of their life due to the energy gains of the renewable energy system. However, the recovery of metal depletion requires 667 years. This result provides evidence of the emerging need for integrating circular processes regarding recycling and reusing materials in construction and also in the energy-generating sector.