Research and practical experience have shown that partial replacement of cement by metakaolin improves concrete durability as a result of the refinement of the pore structure. While much research has been presented on concrete performance with metakaolin, it is scarce concerning the transport properties of chlorides in concrete with metakaolin, in natural conditions (i.e., un-accelerated). This study determines the chloride diffusion coefficients for several concretes with vary levels of cement replacement with metakaolin, and compares these results with chloride migration coefficients obtained from accelerated laboratory testing. In this study, two cement types (CEM I 42,5R and CEM IV/A 42,5) and two cement contents levels where used with metakaolin replacement levels varying from 10-20%. Concretes where tested for fresh properties, compressive strength, electrical resistivity, chloride ingress characteristics (natural diffusion and migration), and mercury intrusion porosimetry. The results show improved strength, durability properties and chloride penetration resistance of concretes with metakaolin. Furthermore, the use of metakaolin in fly ash concrete improves the early age performance of the concrete (<90 days), counteracting the delay in strength and durability gain typically associated with fly ash concrete. The results obtained from this study fulfil the lack of critical input for service life design models of reinforced concrete structures in chloride environments, with emphasis on concretes with metakaolin replacement.

The increase in global environmental problems requires more environmentally efficient construction. Vernacular passive strategies can play an important role in helping reducing energy use and CO₂ emissions related to buildings. This paper studies the use of glazed balconies in the North of Portugal as a strategy to capture solar gains and reduce heat losses. The purpose is understanding thermal performance and comfort conditions provided by this passive heating strategy. The methodology includes objective (short and long-term monitoring), to evaluate the different parameters affecting thermal comfort and air quality, and subjective assessments to assess occupants’ perception regarding thermal sensation. The results show that the use of glazed balconies as a passive heating strategy in a climate with cold winters is viable. During the mid-seasons, the rooms with balcony have adequate comfort conditions. In the heating season, it is possible to achieve comfort conditions in sunny days while in the cooling season there is a risk of overheating. Regarding indoor air quality, carbon dioxide concentrations were low, but the average radon concentration measured was high when the building was unoccupied, rapidly decreasing to acceptable values, during occupation periods when a minimum ventilation rate was promoted. Occupants’ actions were essential to improving building behavior.

Knowing the properties of vernacular materials is crucial to heritage conservation and to develop innovative solutions. Reed, considered to be a carbon-neutral and a carbon dioxide sink material, has been used for centuries for diverse uses. Its high availability and properties made it a popular building material, including in Portuguese vernacular architecture. An experimental investigation was conducted to evaluate the physical performance, thermal performance, and durability of the reed found in Portugal since the characterisation of this material was not found in previous studies. The influence of geometric characteristics and the presence of nodes on these properties were also analysed, and the results showed that they are irrelevant. The studied reeds were found to have an adequate thermal performance to be used as thermal insulation. Their thermal resistance (1.8 m²·°C/W) and thermal conductivity (0.06 W/m·°C) are under the requirements defined by Portuguese regulations on thermal insulation materials. Overall, the physical characteristics (moisture content, density, and retraction) are compatible to its use in the construction. Concerning durability, there was only a trend for mould growth in particular environments. The results provide valuable data to be considered in the development of new construction products based on this natural and renewable material. Additionally, considering the studied samples, the reed found in Portugal has characteristics suitable for use as a building material, especially as a thermal insulation material.

The use of waste as supplementary cementitious materials (SCMs) in concrete is already widespread, with glass waste being an increasingly used option. The utilization of glass waste as a partial substitute for cement in small proportions has shown satisfactory outcomes. Nevertheless, substituting cement in high proportions requires further investigation. Experimental research was carried out on the mechanical and durability properties of concrete with the replacement of cement by glass powder (GP), at a high volume equal to 50%. Binder content (cement plus GP) varied from 300 to 500 kg/m³. The results are promising regarding the use of the high volume of GP in high-performance concretes. The specimens with 500 kg/m³ of binder (50% of which was GP-G250) achieved almost 55 MPa at 28 days. The specimen with the lowest resistance was G150, with 32 MPa. This result may be related to the high pozzolanic activity index of the used GP. The specimens with GP showed satisfactory performance regarding chloride migration, with diffusion coefficients always below those of the reference specimens. The G250 concrete showed a reduction of 58%. Regarding open porosity, concretes with 50% GP had a lower porosity than the reference concretes. The smallest reduction (21%) occurred in the G150 concrete. The reduction in porosity provided by the fineness of the GP may be the main cause of this high performance. Concerning capillary absorption, the GP concretes have a reduction that varies between 47% for G150 and 67% for G250. This fact may be related to the existence of a larger quantity of larger-sized capillary pores in the reference concretes.

A large-scale energy renovation intervention in existing buildings has been consistently presented as the most significant opportunity to contribute to achieving the European targets for 2030 and 2050. One of the key points for such achievement is the cost-effectiveness of the interventions proposed, which is also closely related to decent housing affordability. Prefabricated modular solutions have been pointed out as a pathway, but there are knowledge gaps regarding both its cost-effectiveness and its environmental performance. Considering a social housing multi-family building in Porto, Portugal, as a case study, this research employs energy simulations, a cost-optimal methodology and a life cycle analysis approach to assess the influence of considering embodied energy and emissions in cost-effectiveness calculations. In general terms, the hierarchical relation between calculated renovation scenarios remain identical, as well as the choice of the cost-optimal combination, which can reduce primary energy needs by 226 kWh/(y.m²). However, embodied carbon emissions and embodied energy of the materials used in the calculations, which are indicative of the sustainability of such interventions, increase the energy and carbon emissions associated to each renovation package by an average of 43 kWh/(y.m²) and 9.3 kgCO_2eq/(y.m²), respectively.