Recently, many scientists and polymer engineers have been working on eco-friendly materials for starch-based food packaging purposes, which are based on biopolymers, due to the health and environmental issues caused by the non-biodegradable food packaging. However, to maintain food freshness and quality, it is necessary to choose the correct materials and packaging technologies. On the other hand, the starch-based film’s biggest flaws are high permeability to water vapor transfer and the ease of spoilage by bacteria and fungi. One of the several possibilities that are being extensively studied is the incorporation of essential oils (EOs) into the packaging material. The EOs used in food packaging films actively prevent inhibition of bacteria and fungi and have a positive effect on food storage. This work intended to present their mechanical and barrier properties, as well as the antimicrobial activity of anti-microbacterial agent reinforced starch composites for extending product shelf life. A better inhibition of zone of antimicrobial activity was observed with higher content of essential oil. Besides that, the mechanical properties of starch-based polymer was slightly decreased for tensile strength as the increasing of essential oil while elongation at break was increased. The increasing of essential oil would cause the reduction of the cohesion forces of polymer chain, creating heterogeneous matrix and subsequently lowering the tensile strength and increasing the elongation (E%) of the films. The present review demonstrated that the use of essential oil represents an interesting alternative for the production of active packaging and for the development of eco-friendly technologies.
1 July 2021 in Journal of Materials Research and Technology
In the recent past, significant research effort has been dedicated to examining the usage of nanomaterials hybridized with lignocellulosic fibers as reinforcement in the fabrication of polymer nanocomposites. The introduction of nanoparticles like montmorillonite (MMT) nanoclay was found to increase the strength, modulus of elasticity and stiffness of composites and provide thermal stability. The resulting composite materials has figured prominently in research and development efforts devoted to nanocomposites and are often used as strengthening agents, especially for structural applications. The distinct properties of MMT, namely its hydrophilicity, as well as high strength, high aspect ratio and high modulus, aids in the dispersion of this inorganic crystalline layer in water-soluble polymers. The ability of MMT nanoclay to intercalate into the interlayer space of monomers and polymers is used, followed by the exfoliation of filler particles into monolayers of nanoscale particles. The present review article intends to provide a general overview of the features of the structure, chemical composition, and properties of MMT nanoclay and lignocellulosic fibers. Some of the techniques used for obtaining polymer nanocomposites based on lignocellulosic fibers and MMT nanoclay are described: (i) conventional, (ii) intercalation, (iii) melt intercalation, and (iv) in situ polymerization methods. This review also comprehensively discusses the mechanical, thermal, and flame retardancy properties of MMT-based polymer nanocomposites. The valuable properties of MMT nanoclay and lignocellulose fibers allow us to expand the possibilities of using polymer nanocomposites in various advanced industrial applications.
In this study, the effect of sugar palm nanocrystalline cellulose (SPNCC) loading (0.00–0.10 wt %) on the electrical resistance, resistivity, and conductivity of SPS/SPNCC (SPS – sugar palm starch) nanocomposite films were evaluated. The experiments were conducted using the four-probe method and Ohm’s law, resistivity and conductivity equations were utilized to obtain the electrical properties. The results revealed that the resistivity values of SPS/SPNCC films were found to be in the range of 3.1 · 102 to 1.5 · 104 (Ω · cm).
This research aims to determine the mechanical properties of sugar palm fiber (Arenga pinnata Wurmb. Merr) (SPF)/glass fiber (GF)-reinforced poly(lactic acid) (PLA) hybrid composites for potential use in motorcycle components. The mechanical (hardness, compressive, impact, and creep) and flammability properties of SPF/GF/PLA hybrid composites were investigated and compared to commercially available motorcycle Acrylonitrile Butadiene Styrene (ABS) plastic components. The composites were initially prepared using a Brabender Plastograph, followed by a compression molding method. This study also illustrated the tensile and flexural stress–strain curves. The results revealed that alkaline-treated SPF/GF/PLA had the highest hardness and impact strength values of 88.6 HRS and 3.10 kJ/m2, respectively. According to the results, both alkaline and benzoyl chloride treatments may improve the mechanical properties of SPF/GF/PLA hybrid composites, and a short-term creep test revealed that the alkaline treated SPF/GF/PLA composite displayed the least creep deformation. The findings of the horizontal UL 94 testing indicated that the alkaline-treated SPF/GF/PLA hybrid composites had good flame resistance. However, alkaline-treated SPF/GF/PLA composites are more suitable materials for motorcycle components.