This paper presents the results of investigating the dynamics of an economic system with chaotic behavior and a suboptimal control proposal to suppress the chaotic behavior. Numerical results using phase portraits, bifurcation diagrams, Lyapunov exponents, and 0-1 testing confirmed chaotic and hyperchaotic behavior. The results also proved the effectiveness of the control, showing errors below 1%, even in cases where the control design is subject to parametric errors. Additionally, an investigation of the system in fractional order is included, demonstrating that the system has periodic, constant, or chaotic behavior for specific values of the order of the derivative.

The sustainability of cities is a challenge due to the growth, functioning, and needs of the population. In this context, the concept of the smart city has gained prominence worldwide in the last decades. In Brazil, it has also drawn attention driven by technological advances and the search for innovative solutions to urban challenges. Several different reports were created aiming to assess and categorize the advancement of cities in this regard. Some of them established their own indicators for this evaluation, whereas others are based on standards ISO 37120 and ISO 37122. The focus of this study revolves around the examination of indicators presently utilized, which may be influenced by initiatives grounded in the principles of green chemistry (PGCs). Furthermore, it explores how these principles can aid in the realization of the targets outlined in the Sustainable Development Goals (SDGs) set forth by the United Nations. Two case studies are presented, the first pointing out how PGCs and SDGs can correlate with smart city reporting indicators. The second is a case study centered on the Brazilian city of Curitiba (PR). We aim to exemplify how the city’s action plans underscore the significance of synergy among the principles of green chemistry, the objectives of sustainable development, and indicators for smart cities. Assessing how chemically green a city can be is a relevant argument for future industrial installations and stakeholders and the influence of this index on the quality of life of its population. Such an approach not only fosters innovation and efficiency but also fosters environmental stewardship, thus contributing to overall sustainability.

In recent years, the number of motor vehicles in circulation has increased in proportion to Brazil’s economic growth, resulting in an increase in emissions of toxic gases from combustion, such as nitrogen oxide, particulate matter, carbon dioxide and volatile organic compounds, among other polluting compounds. This type of pollution has its impacts potentiated in large cities, accumulating due to the configuration of streets and buildings in large urban centers, and can even penetrate indoor environments, having harmful effects on the health of residents. To minimize the emission of these gases, catalytic converters can be used in the vehicle exhausts. Catalytic converters are a promising technology used to reduce exhaust emissions from the engine. In this context, this paper presents an overview of the emission of toxic gases by heavy transport powered by diesel oil and the influence of the use of automotive catalysts in reducing the emission of toxic gases. Additionally, a proposal for monitoring the useful life of automotive catalysts is presented through an electronic sensing system, which makes it possible to determine the catalyst efficiency and the appropriate point for its reactivation or replacement.

In the present work, the performance of Ag/ZnO/CoFe2O4 magnetic photocatalysts in the photocatalytic degradation of ibuprofen (IBP) was evaluated. This study considered the use of pure Ag/ZnO (5% Ag) and also the use of the Ag/ZnO/CoFe2O4 magnetic catalysts containing different amounts (5, 10 and 15% wt) of cobalt ferrite (CoFe2O4). The catalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and photoacoustic spectroscopy. To carry out the photocatalytic degradation reaction, different concentrations of the ibuprofen contaminant solution (10, 20 and 30 ppm) and different concentrations of photocatalyst were tested (0.3 g L−1, 0.5 g L−1 and 1.0 g L−1). The reaction parameters studied were: IBP concentration, catalyst concentration, adsorption and photolysis, influence of the matrix, radiation source (solar and artificial) and the effect of organic additive. At the end of the photocatalytic tests, the best operating conditions were defined. Considering the obtained results of degradation efficiency and magnetic separation, the optimal parameters selected to proceed with the other tests of the study were: ibuprofen solution concentration 10 ppm, Ag/ZnO/CoFe2O4 (5%) catalyst at a concentration of 0.3 g L−1 and pH 4.5 of the reaction medium. The results indicated the feasibility of magnetic separation of the synthesized catalysts. A long duration test indicated that the catalyst exhibits stability throughout the degradation reaction, as more than 80% of IBP was degraded after 300 minutes. The photocatalytic activity was directly affected by the ferrite load. The higher the nominal load of ferrite, the lower the performance in IBP degradation. It was also observed that the smallest amount of ferrite studied was enough for the catalyst to be recovered and reused. The adsorption and photolysis tests did not show significant results in the IBP degradation. In addition, it was possible to verify that the aqueous matrix, the use of solar radiation and the addition of additive (acid formic) were interfered directly in the process. The catalyst reuse tests indicated that it can be recovered and reused at least three times without considerable catalytic activity loss.

This paper investigates, through numerical simulations, the application of piezoelectric materials in energy generation. The mathematical model describes a U-shaped portal frame system, excited by an engine with unbalanced mass and coupled to a nonlinear energy sink (NES), which is used as a passive vibration absorber. The influence of the piezoelectric material parameters used in the energy collection and the dimensioning parameters of the NES system is deeply analyzed in this paper. Numerical simulations are presented considering all combinations of the parameters of the piezoelectric material model and the NES. The system dynamics were analyzed through phase diagrams and the 0–1 test. The estimation of energy collection was carried out by calculating the average power. The numerical results show that a more significant potential for energy generation is obtained for certain combinations of parameters, as well as chaotic behavior in some cases.