Polymers are widely used in many areas, but often their individual properties are not sufficient for use in certain applications. One of the solutions is the creation of polymer-based composites and nanocomposites. In such materials, in order to improve their properties, nanoscale particles (at least in one dimension) are dispersed in the polymer matrix. These properties include increased mechanical strength and durability, the ability to create a developed inner surface, adjustable thermal and electrical conductivity, and many others. The materials created can have a wide range of applications, such as biomimetic materials and technologies, smart materials, renewable energy sources, packaging, etc. This article reviews the usage of composites as a matrix for the optical sensors and biosensors. It highlights several methods that have been used to enhance performance and properties by optimizing the filler. It shows the main methods of combining indicator dyes with the material of the sensor matrix. Furthermore, the role of co-fillers or a hybrid filler in a polymer composite system is discussed, revealing the great potential and prospect of such matrixes in the field of fine properties tuning for advanced applications.

Post-consumer poly(ethylene terephthalate) (PET) waste disposal is an important task of modern industry, and the development of new PET-based value added products and methods for their production is one of the ways to solve it. Membranes for various purposes, in this regard are such products. The aim of the review, on the one hand, is to systematize the known methods of processing PET and copolyesters, highlighting their advantages and disadvantages and, on the other hand, to show what valuable membrane products could be obtained, and in what areas of the economy they can be used. Among the various approaches to the processing of PET waste, we single out chemical methods as having the greatest promise. They are divided into two large categories: (1) aimed at obtaining polyethylene terephthalate, similar in properties to the primary one, and (2) aimed at obtaining copolyesters. It is shown that among the former, glycolysis has the greatest potential, and among the latter, destruction followed by copolycondensation and interchain exchange with other polyesters, have the greatest prospects. Next, the key technologies for obtaining membranes, based on polyethylene terephthalate and copolyesters are considered: (1) ion track technology, (2) electrospinning, and (3) non-solvent induced phase separation. The methods for the additional modification of membranes to impart hydrophobicity, hydrophilicity, selective transmission of various substances, and other properties are also given. In each case, examples of the use are considered, including gas purification, water filtration, medical and food industry use, analytical and others. Promising directions for further research are highlighted, both in obtaining recycled PET-based materials, and in post-processing and modification methods.

A method for producing nanocomposites of unsaturated polyester resins (UPR) based on recycled polyethylene terephthalate (PET) as a matrix has been proposed. The upcycling method involves three successive stages: (1) oligoesters synthesis, (2) simultaneous glycolysis and interchain exchange of oligoesters with PET, (3) interaction of the obtained resins with glycol and maleic anhydride. UPRs were characterized by FTIR spectroscopy and gel permeation chromatography. The mechanical properties of nanocomposites obtained on the basis of these resins and titanium dioxide have been investigated. It has been shown that 1,2-propylene glycol units, despite their lower reactivity, significantly improve the properties of UPR. The most promising nanocomposite sample exhibited tensile strength 112.62 MPa, elongation at break 157.94%, and Young’s modulus 29.95 MPa. These results indicate that the proposed method made it possible to obtain nanocomposites with high mechanical properties based on recycled PET thus allowing one to create a valuable product from waste.

In the last decade, there has been continuous competition between two methods for detecting the concentration of dissolved oxygen: amerometric (Clark electrode) and optical (quenching of the phosphorescence of the porphyrin metal complex). Each of them has obvious advantages and disadvantages. This competition is especially acute in the development of biosensors, however, an unbiased comparison is extremely difficult to achieve, since only a single detection method is used in each particular study. In this work, a microfluidic system with synchronous detection of the oxygen concentration by two methods was created for the purpose of direct comparison. The receptor element is represented by Saccharomyces cerevisiae yeast cells adsorbed on a composite material, previously developed by our scientific group. To our knowledge, this is the first work of this kind in which the comparison of the oxygen detection methods is carried out directly.

Lactide is one of the most popular and promising monomers for the synthesis of biocompatible and biodegradable polylactide and its copolymers. The goal of this work was to carry out a full cycle of polylactide production from lactic acid. Process conditions and ratios of reagents were optimized, and the key properties of the synthesized polymers were investigated. The influence of synthesis conditions and the molecular weight of lactic acid oligomers on the yield of lactide was studied. Lactide polymerization was first carried out in a 500 mL flask and then scaled up and carried out in a 2000 mL laboratory reactor setup with a combined extruder. Initially, the lactic acid solution was concentrated to remove free water; then, the oligomerization and synthesis of lactide were carried out in one flask in the presence of various concentrations of tin octoate catalyst at temperatures from 150 to 210 °C. The yield of lactide was 67–69%. The resulting raw lactide was purified by recrystallization in solvents. The yield of lactide after recrystallization in butyl acetate (selected as the optimal solvent for laboratory purification) was 41.4%. Further, the polymerization of lactide was carried out in a reactor unit at a tin octoate catalyst concentration of 500 ppm. Conversion was 95%; Mw = 228 kDa; and PDI = 1.94. The resulting products were studied by differential scanning calorimetry, NMR spectroscopy and gel permeation chromatography. The resulting polylactide in the form of pellets was obtained using an extruder and a pelletizer.