The goal of the tests was to separate a phosphate concentrate from ash and to assess its fertiliser use efficiency in anthropogenic land. Ash obtained from poultry manure incineration is an interesting fertiliser, as it contains both of the necessary nutrients, i.e., phosphorus and potassium. The ash selected for the tests contained 15.73 wt% P₂O₅, and 6.75 wt% K₂O. CaO also constituted the main component (44.79 wt%). Phosphorus in crystalline form was present as hydroxyapatite and carbonate apatite. The first stage, applied in order to separate a phosphate concentrate from ash, involved a number of physicochemical methods: (i) a method based on grain wettability differences; (ii) a method based on grain density differences; and (iii) methods based on size distribution differences. Wet sieving made it possible to separate a fraction with a P₂O₅ content of 24.56 wt%. The second stage, applied to assess fertiliser use efficiency, involved cassette tests as well as pot and field cultivation using as fertiliser, the obtained product as well as raw ash and commercial ones. Therefore, the conducted research allowed for the development of a methodology for the management of ash from the incineration of a poultry manure and their use as a substitute for phosphorus fertiliser. The tested material was applied in various doses. Using the obtained phosphate concentrate at a dose of 95 g/m³ resulted in a comparable yield as in the case of the commercial fertiliser at a dose recommended by the producer (75 g/m³). Unprocessed ash had to be used in larger amounts, i.e., 165 g/m³, to have a comparable yield as a commercial fertiliser.

The aim of this study was to examine the physico-chemical and phase characteristics of ash obtained in the process of the combustion of Polish poultry manure in a laboratory reactor with a bubbling fluidized bed. Three experiments, differing in the grain size and morphology of the raw material, the method of its dosing and the type of fluidized bed, were carried out. The contents of the main chemical components and trace elements in the obtained ash samples were determined using WDXRF, and the phase composition was examined through the XRD method. The morphology and the chemical composition of grains in a given micro-area using the SEM/EDS method were also investigated. The highest concentration of phosphorus (from 28.07% wt. to 29.71% wt. as P₂O₅ equivalent), the highest proportion of amorphous substance (from 56.7% wt. to 59.0% wt.) and the lowest content of unburned organic substance (LOI from 6.42% to 9.16%) (i.e., the best process efficiency), was obtained for the experiment in which the starting bed was quartz sand and poultry manure was fed to the reactor in the form of pellets. It has been calculated that in this case, the amorphous phase contains more than half of the phosphorus. The method of carrying out the combustion process has a significant impact on the phase composition and, consequently, on the availability of phosphorus.

Coal gasification is a complex process of parallel-consecutive chemical reactions at high temperature between the organic part of coal matter and the gasifying agent. The following two approaches are applied in modelling the coal gasification process: equilibrium and kinetic. The methods of determining the thermodynamic equilibrium can be divided into two groups: stoichiometric and non-stoichiometric methods. This article presents the equilibrium model of the steam gasification of coal developed for a laboratory experiment (Smoliński 2008, 2011). The scope of this paper includes the development of the concept concerning the division of the reaction system into two zones, where the result of one of the stages constitutes the input data for the subsequent stage. The composition of the gas mixture has been evaluated on the basis of the fundamental physical and chemical rights. The estimated content of the gases in the mixture correlate with the results of the experiment.