Anodizing a simple and effective method to improve the wear resistance of 6061 aluminum alloy. In this study, the microstructure of 6061 aluminum alloy oxide films (AAO) was adjusted by changing the electrolyte temperature (5, 15, and 25 °C) using 160 g/L sulfuric acid as the electrolyte. The phase composition, microstructure, and morphological characteristics of the specimens were detected using X-ray diffractometer and field emission scanning electron microscopy (SEM). The hardness, elastic modulus, and tribological properties of the films were examined using hardness testers and a rotary friction tester. The results showed that as the temperature of the electrolyte increases, the surface of the oxide films changes from uniformly distributed small-sized pores to a coral-like loose porous structure, and the thickness of the films increases. The electrolyte temperature has a significant effect on the friction performance of the AAO films. When the solution temperature decreases from 25 to 5 °C, the steady-state friction coefficient decreases from 0.46 to 0.39. According to the morphology of the wear tracks, it can be determined that the main wear mechanism of AAO films gradually changes from delamination wear to abrasive and adhesive wear, and the wear rate drops by ~69%.
Numerical calculations of ultraviolet to near-infrared absorption spectra by cadmium selenide quantum dots (CdSe QDs) doped in anodic aluminum oxide pores were performed using a finite-difference time-domain model. The height, diameter, and periodic spacing of the pores were optimized. Light absorption by the dots was enhanced by increasing the height and decreasing the diameter of the pores. When the height was less than 1 μm, visible light absorption was enhanced as the spacing was reduced from 400 nm to 100 nm. No enhancement was observed for heights greater than 6 μm. Finally, the optical mode coupling of the aluminum oxide and the quantum dots was enhanced by decreasing the pore diameter and periodic spacing and increasing the height. Laser ablation verified light absorption enhancement by the CdSe QDs. The experiments verified the improvement in the laser-induced damage ability with a nanosecond laser at a wavelength of 355 nm after aluminum alloy 6061 was coated with functional films and fabricated based on numerical calculations.