An agricultural waste-based source of energy in the form of briquettes from rice husk has emerged as an alternative energy source. However, rice husk-based briquette has a low bulk density and moisture content, resulting in low durability. This study investigated the effect of initial moisture contents of 12%, 14%, and 16% of rice husk-based briquettes blended with 10 wt% of kraft lignin on their chemical and physical characteristics. The briquetting was done using a hand push manual die compressor. The briquette properties were evaluated by performing chemical (ultimate and proximate analysis, thermogravimetric analysis), physical (density, durability, compressive strength, and surface morphology) analyses. The durability values of all briquette samples were above 95%, meeting the standard with good compressive strength, surface morphology, and acceptable density range. The briquette made from the blend with 14% moisture content showed the highest calorific value of 17.688 MJ kg−1, thanks to its desirable morphology and good porosity range, which facilitates the transport of air for combustion. Overall, this study proved the approach of enhancing the quality of briquettes from rice husk by controlling the moisture content.
Pollution from dye containing wastewater leads to a variety of environmental problems, which can destroy plant life and eco-systems. This study reports development of a seaweed-based biochar as an adsorbent material for efficient adsorption of methylene blue (MB) dye from synthetic wastewater. The Eucheuma cottonii seaweed biochar was developed through pyrolysis using a tube furnace with N2 gas, and the properties were later improved by sulfuric acid treatment. The adsorption studies were conducted in a batch experimental setup under initial methylene blue concentrations of 50 to 200 mg/L, solution pH of 2 to 10, and temperature of 25 to 75 °C. The characterization results show that the developed biochar had a mesoporous pore morphology. The adsorbent possessed the surface area, pore size, and pore volume of 640 m2/g, 2.32 nm, and 0.54 cm3/g, respectively. An adsorption test for 200 mg/L of initial methylene blue at pH 4 showed the best performance. The adsorption data of the seaweed-based biochar followed the Langmuir isotherm adsorption model and the pseudo-second-order kinetic model, with the corresponding R2 of 0.994 and 0.995. The maximum adsorption capacity of methylene blue using the developed seaweed‑based biochar was 133.33 mg/g. The adsorption followed the chemisorption mechanism, which occurred via the formation of a monolayer of methylene blue dye on the seaweed-based biochar surface. The adsorption performance of the produced seaweed biochar is comparable to that of other commercial adsorbents, suggesting its potential for large-scale applications.
Development of strategies for removing heavy metals from aquatic environments is in high demand. Cadmium is one of the most dangerous metals in the environment, even under extremely low quantities. In this study, kenaf and magnetic biochar composite were prepared for the adsorption of Cd2+. The synthesized biochar was characterized using (a vibrating-sample magnetometer VSM), Scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). The adsorption batch study was carried out to investigate the influence of pH, kinetics, isotherm, and thermodynamics on Cd2+ adsorption. The characterization results demonstrated that the biochar contained iron particles that help in improving the textural properties (i.e., surface area and pore volume), increasing the number of oxygen-containing groups, and forming inner-sphere complexes with oxygen-containing groups. The adsorption study results show that optimum adsorption was achieved under pH 5–6. An increase in initial ion concentration and solution temperature resulted in increased adsorption capacity. Surface modification of biochar using iron oxide for imposing magnetic property allowed for easy separation by external magnet and regeneration. The magnetic biochar composite also showed a higher affinity to Cd2+ than the pristine biochar. The adsorption data fit well with the pseudo-second-order and the Langmuir isotherm, with the maximum adsorption capacity of 47.90 mg/g.
A rotating biological contactor (RBC) is a type of attached-growth biological wastewater treatment system and a widely used biological wastewater treatment technology. It employs a series of rotating discs to support microbial growth and promote the removal of pollutants from wastewater. RBC is widely recognized for its simplicity of design, high reliability, and low energy consumption. It has been used in various applications, from small-scale decentralized systems to large municipal wastewater treatment plants. The current review provides an overview of RBC bioreactors, design parameters, and the factors that influence biological performance, such as hydraulic retention time, sludge retention time, organic loading rate, disc rotational speed, and temperature. The review also highlights the advantages and disadvantages of RBCs compared with other wastewater treatment technologies and discusses their role in sustainable environmental performance. The future prospects of RBC are also discussed, including integration with other technologies, such as membrane filtration and potential use in resource recovery. The review explores the application of RBC in decentralized wastewater treatment and the potential to provide sustainable solutions for wastewater management in rural and remote areas. Overall, RBC remains a promising option for effective and efficient wastewater treatment, particularly in situations where simplicity, reliability, and low energy consumption are desired.
Integrated fixed-film activated sludge (IFAS) is a hybrid wastewater treatment process that combines suspended and attached growth. The current review provides an overview of the effect of operating parameters on the performance of IFAS and their implications for wastewater treatment. The operating parameters examined include hydraulic retention time (HRT), solids retention time (SRT), dissolved oxygen (DO) levels, temperature, nutrient loading rates, and aeration. Proper control and optimization of these parameters significantly enhance the treatment efficiency and pollutant removal. Longer HRT and appropriate SRT contribute to improved organic matter and nutrient removal. DO levels promote the growth of aerobic microorganisms, leading to enhanced organic matter degradation. Temperature influences microbial activity and enzymatic reactions, impacting treatment efficiency. Nutrient loading rates must be carefully managed to avoid system overload or inhibition. Effective aeration ensures uniform distribution of wastewater and biofilm carriers, optimizing contact between microorganisms and pollutants. IFAS has been used in water reuse applications, providing a sustainable and reliable water source for non-potable uses. Overall, IFAS has proven to be an effective and efficient treatment process that can provide high-quality effluent suitable for discharge or reuse. Understanding the effects of these operating parameters helps to optimize the design and operation for efficient wastewater treatment. Further research is needed to explore the interactions between different parameters, evaluate their impact under varying wastewater characteristics, and develop advanced control strategies for improved performance and sustainability.