The study investigates the phytochemical profile, antioxidant capacity, and antimicrobial activities of ethanol (ChL-EtOH) and ethyl acetate (ChL-EtOAc) extracts from Chamaenerion latifolium L. (ChL) harvested in Kazakhstan. The ChL-EtOH extract exhibited higher total phenolic (267.48 ± 3.44 mg GAE/g DE) and flavonoid content (24.18 ± 1.06 mg QE/g DE) compared to ChL-EtOAc. HPLC-UV-ESI/MS identified key phenolic acids and flavonoids, including gallic acid, chlorogenic acid, and quercetin 3-glucoside. FT-IR analysis confirmed the presence of characteristic functional groups. Antioxidant assays revealed strong DPPH scavenging and FRAP activities, with ChL-EtOH showing superior results (IC₅₀ = 21.31 ± 0.65 μg/mL and 18.13 ± 0.15 μg/mL, respectively). Additionally, ChL-EtOH displayed notable antimicrobial efficacy against Gram-positive and Gram-negative bacteria, as well as the fungal strain Candida albicans. These findings suggest that ethanol extraction is more efficient for isolating bioactive compounds from ChL, underscoring its potential for pharmaceutical and nutraceutical applications.

Understanding the efficiency of different wastewater treatment technologies tested under real conditions is essential for successful decision making by engineers and managers. In this study, real poultry slaughterhouse wastewater coming from defeathering, cooling, and evisceration processes was treated using a lab-scale electrochemical process by use of iron-iron (Fe-Fe), iron-graphite (Fe-Gr) and aluminum-graphite (Al-Gr) electrode combinations. A water quality index (WQI) was developed and used as a tool for evaluating and classifying the effectiveness of different electrode combinations. The Al-Gr electrode combination showed an impressive performance achieving an “excellent” status for all of the three studied sources of wastewater with a WQI ranging from 13 to 34. The Fe-Gr electrode combination showed an “excellent” status performance for the wastewater from the cooling process as classified by the WQI and “good water” class for the defeathering and evisceration processes. The lower performance, which was highly affected by the increase in turbidity, was observed for the Fe-Fe electrode combination with a “poor water” status for the wastewater coming from defeathering and cooling processes and “good water” status for evisceration process.

In the current decade, the use of plant extracts for the green preparation of metal nanoparticles has garnered increasing attention due to their eco-friendliness, cost-effectiveness, and sustainability. In the current study, silver nanoparticles (AgNPs) were synthesized using the ethanolic extract of Circaea lutetiana for the first time. Thetotal flavonoid content (TFC) and total phenolic content (TPC)of the extract were analyzed by spectrophotometric methods. Fourier transform infrared (FT-IR) spectroscopy was employed to determine the functional groups involved in both the reduction and stabilization processes of AgNPs. The formation and optical properties of AgNPs were confirmed by Ultraviolet–Visible (UV–Vis) spectroscopy. The greenlysynthesized AgNPs were characterized by FT-IR, UV–Vis, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), dynamic light scattering (DLS) and zeta potential analyses, transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The results confirmed that the AgNPs were spherical in shape with an average size of approximately 3.8 nm and showed a good crystalline nature. Additionally, the AgNPs exhibited significant antimicrobial activity against both Gram-positive and Gram-negative bacteria, demonstrating their potential as green antimicrobial agents.

Poultry slaughterhouse wastewater is characterized by high pollution strength, making its treatment before discharge or recycling of great importance. This study investigated the potential influence of mixing ratios on the treatability of poultry slaughterhouse wastewater under three different mixing ratios; 20:80, 50:50, and 80:20 of defeathering and cooling sources, respectively. Wastewater samples were collected from the Izhevski production corporate (PC) poultry farm located in the Akmola region, Kazakhstan. The lab-scale treatment plant, designed to simulate the industrial-scale treatment plant of the poultry farm, consists of electrolysis, membrane filtration, and ultraviolet disinfection as the main units. The general design purpose of the Izhevski PC treatment plant is to treat about 1.25 m³/h (51.72%) of the total wastewater generated from the defeathering and cooling sections of the slaughterhouse to a recyclable degree. Water quality indices (WQIs) were developed for each of the studied mixing ratios. A comparative analysis was also done with drinking water quality standards set by the World Health Organization (WHO), as well as the government of Kazakhstan. From the analysis results, the defeathering raw wastewater was generally higher in pollution strength than the cooling wastewater. It was also observed that the increase in the ratio of defeathering wastewater reduced treatment efficiency for some physicochemical parameters such as turbidity, total suspended solids (TSS), color, biochemical oxygen demand (BOD), as well as chemical oxygen demand (COD). However, 100% removal efficiency was achieved for the microbial parameters for all the three studied ratios. Based on the computed WQIs, the highest-quality effluent was achieved from the 20:80 (defeathering:cooling) mixing ratio. However, with the fact that all the three mixing ratios produced “excellent” status, the 80:20 (defeathering:cooling) mixing ratio stands to be an ideal option. The selection of 80:20 mixing ratio has the potential to reduce the pollution load in the wastewater discharged to the sewerage system, while achieving high-quality effluent for recycling in the cooling processes of the slaughterhouse.

A library of bidentate diols, as well as tridentate triols and aminodiols, derived from (+)-sabinol, was synthesized in a stereoselective manner. Sabinol was transformed into allylic trichloroacetamide via Overman rearrangement of the corresponding trichloroacetimidate. After changing the protecting group to Boc, the enamine was subjected to stereospecific dihydroxylation with OsO₄/NMO, resulting in the (1R,2R,3R,5R)-aminodiol diastereomer. The obtained primary aminodiol was transformed to a secondary analogue. The ring closure of the N-benzyl-substituted aminodiol with formaldehyde was investigated and regioselective formation of the spiro-oxazolidine ring was observed. Hydroboration or dihydroxylation of sabinol or its benzyl ether with OsO₄/NMO resulted in the formation of sabinane-based diols and triols following a highly stereospecific reaction. Treatment of sabinol with m-CPBA afforded O-benzoyl triol as a diastereoisomer of the directly dihydroxylated product, instead of the expected epoxy alcohol. The resulting aminodiols, diol, and triols were applied as chiral catalysts in the reaction of diethylzinc and benzaldehyde from moderate to good selectivity.

In this study, we synthesized a ternary transition metal sulfide, Zn_0.76Co_0.24S (ZCS-CE), using a one-step solvothermal method and explored its potential as a Pt-free counter electrode for dye-sensitized solar cells (DSSCs). Comprehensive investigations were conducted to characterize the structural, morphological, compositional, and electronic properties of the ZCS-CE electrode. These analyses utilized a range of techniques, including X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The electrocatalytic performance of ZCS-CE for the reduction of I₃⁻ species in a symmetrical cell configuration was evaluated through electrochemical impedance spectroscopy and cyclic voltammetry. Our findings reveal that ZCS-CE displayed superior electrocatalytic activity and stability when compared to platinum in I⁻/I₃⁻ electrolyte systems. Furthermore, ZCS-CE-based DSSCs achieved power conversion efficiencies on par with their Pt-based counterparts. Additionally, we expanded the applicability of this material by successfully powering an electrochromic cell with ZCS-CE-based DSSCs. This work underscores the versatility of ZCS-CE and establishes it as an economically viable and environmentally friendly alternative to Pt-based counter electrodes in DSSCs and other applications requiring outstanding electrocatalytic performance.