Chitosan is a promising environment friendly active polymer packaging material due to its biodegradability, exceptional film forming capacity, great mechanical strength, appropriate barrier property along with intrinsic antioxidant and antimicrobial features. Bifunctional reagent was used for producing water insoluble chitosan films. Biopolymeric films crosslinked by Genipin (Gp), which is a reagent of natural origin, should have high potential in food packaging. The influence of the ratio of functional groups in the chitosan-Gp system on film absorption in the visible and ultraviolet regions of the spectrum, sorption, physical, and mechanical properties of the films has been studied. The degree of chitosan crosslinking in the films obtained from solutions containing Gp was estimated using the experimental data on film swelling and water vapor sorption isotherms. It is demonstrated that crosslinking with genipin improves swelling, water resistance, and mechanical properties of the films.

In the present work, the effect of divinylbenzene (DVB) on the kinetics of post-radiation chemical graft polymerization styrene (St) on polyethylene (PE) film and its structural and morphological features were investigated. It has been found that the dependence of the degree of polystyrene (PS) grafting on the DVB concentration in the solution is extreme. An increase in the rate of graft polymerization at low concentrations of DVB in the solution is associated with a decrease in the mobility of the growing chains of PS. A decrease in the rate of graft polymerization at high concentrations of DVB is associated with a decrease in the rate of diffusion of St and iron(II) ions in the cross-linked network structure of macromolecules of graft PS. A comparative analysis of the IR transmission and multiple attenuated total internal reflection spectra of the films with graft PS shows that graft polymerization of St in the presence of DVB leads to the enrichment of the film surface layers in PS. These results have been confirmed by the data on the distribution of sulfur in these films after sulfonation. The micrographs of the surface of the grafted films show the formation of cross-linked local microphases of PS with fixed interfaces.

The study of spectra of internal friction $\lambda =f\left(T\right)$ and temperature dependencies of frequency of freely damped $\nu =f\left(T\right)$ oscillatory process excited in investigated samples of polyethylene with different degree of crystallinity in the temperature range from −150 ${}^{°}$C to +150 ${}^{°}$C. It is established that four local dissipative processes of different intensity shown in different temperature intervals are observed on the spectra $\lambda =f\left(T\right)$. These are $\mu$, $\beta$, $\alpha$, ${\beta }_k$ processes. The theoretical analysis of the relationship between the anomalous changes of the vibrational process frequency $\nu =f\left(T\right)$ and the shift modulus defect $\Delta G=f\left(T\right)$ and the internal friction mechanisms for each of the dissipative loss processes detected on the spectrum $\lambda =f\left(T\right)$ is carried out. The influence of supramolecular structures on local dissipative ${\beta }_k$ process in polyethylene is estimated.

A comparative study of anticorrosive inhibited polymer films on the tungsten surface formed from an aqueous solution of inhibited formulations (INFOR) containing organosilane and corrosion inhibitors was carried out by means of the prolonged exposure of a tungsten product in a modifying solution and by the method of cataphoretic deposition (CPD). Depending on the method of forming films on tungsten, the molecular organization of the near-surface layers was studied (ATR-FTIR), and the subprimary structure of the films was explored (TEM). The optimal modes of cataphoresis deposition (CPD duration and current density applied to the sample) for the formation of a protective inhibited polymer film on the tungsten surface were established by means of SEM. The energy and thermochemical characteristics (sessile drop and DSC methods), as well as operational (adhesive behavior) and protective filming ability (EIS and corrosion behavior), according to the method of formation of inhibited polymer film, were determined. Based on the combined characteristics of the films obtained by the two methods and the deposition modes, the CPD method showed better performance than the electroless dipping method.

The aim of the study is to investigate the influence of the physicochemical characteristics of the molecular and supramolecular structure of polymers on electroadhesive interactions and their change under the action of a constant electric field. Currently, this effect is modeled in electroadhesion studies, but the range of variable parameters is limited and includes permittivity, moisture content, and surface roughness. It is important to consider other physicochemical parameters, such as material crystallinity and surface characteristics, changes in which can affect the magnitude of electroadhesive forces. In this study, the electric field strength was varied by altering the constant voltage in the range of 3–8 kV. Polyethylene, ethylene-vinyl acetate copolymers, and polyvinyl acetate were used as substrates for adhesive systems. The influence of the concentration of vinyl acetate groups, which determine the energy characteristics of the surface, and the degree of crystallinity on electroadhesive interactions under conditions of an external constant electric field and without it was traced. The degree of crystallinity was varied both by the cooling rate and the orientation during drawing. It was shown that by changing the polar component of the surface energy and the proportion of the crystalline phase in the substrate, electroadhesive interactions can be increased by 4 times to 120 Pa compared to polyethylene. The obtained laws are explained by the local dipoles induced by polar functional groups, which enhance the polymer’s surface interactions with other materials and external fields. At the same time, the fixation of macromolecules in crystalline regions complicates polarization under the influence of an electric field.

More than five hundred images of individual macromolecules of random styrene-butadiene copolymers and styrene-isoprene block copolymers dissolved in a polystyrene matrix were analyzed. The presence of density fluctuations inside the macromolecular coil has been established. Within the framework of the model of harmonic oscillations, the radial distribution of such density fluctuations is estimated.