Additive manufacturing (AM) processes can produce three-dimensional (3D) near-net-shape parts based on computer-aided design (CAD) models. Compared to traditional manufacturing processes, AM processes can generate parts with intricate geometries, operational flexibility and reduced manufacturing time, thus saving time and money. On the other hand, AM processes face complex issues, including poor surface finish, unwanted microstructure phases, defects, wear tracks, reduced corrosion resistance and reduced fatigue life. These problems prevent AM parts from real-time operational applications. Post-processing techniques, including laser shock peening, laser polishing, conventional machining methods and thermal processes, are usually applied to resolve these issues. These processes have proved their capability to enhance the surface characteristics and physical and mechanical properties. In this study, various post-processing techniques and their implementations have been compiled. The effect of post-processing techniques on additively manufactured parts has been discussed. It was found that laser shock peening (LSP) can cause severe strain rate generation, especially in thinner components. LSP can control the surface regularities and local grain refinement, thus elevating the hardness value. Laser polishing (LP) can reduce surface roughness up to 95% and increase hardness, collectively, compared to the as-built parts. Conventional machining processes enhance surface quality; however, their influence on hardness has not been proved yet. Thermal post-processing techniques are applied to eliminate porosity up to 99.99%, increase corrosion resistance, and finally, the mechanical properties’ elevation. For future perspectives, to prescribe a particular post-processing technique for specific defects, standardization is necessary. This study provides a detailed overview of the post-processing techniques applied to enhance the mechanical and physical properties of AM-ed parts. A particular method can be chosen based on one’s requirements.

Powder flow and temperature distribution are recognized as essential factors in the laser melting deposition (LMD) process, which affect not only the layer formation but also its characteristics. In this study, two mathematical models were developed. Initially, the three-jet powder flow in the Gaussian shape was simulated for the LMD process. Next, the Gaussian powder flow was coaxially added along with the moving laser beam to investigate the effect of powder flow on temperature distribution at the substrate. The powder particles’ inflight and within melt-pool heating times were controlled to avoid vapors or plasma formation due to excessive heat. Computations were carried out via MATLAB software. A high-speed imaging camera was used to monitor the powder stream distribution, experimentally, while temperature distribution results were compared with finite element simulations and experimental analyses. A close correlation was observed among analytical computation, numerical simulations, and experimental results. An investigation was conducted to investigate the effect of the focal point position on powder stream distribution. It was found that the focal point position plays a key role in determining the shape of the powder stream, such that an increment in the distance from the focus point will gradually transform the powder stream from the Gaussian to Transition, and from the Transition to Annular streams. By raising the powder flow rate, the attenuation ratio prevails in the LMD process, hence, decreasing the laser energy density arriving at the substrate. The computations indicate that, if the particle’s heating temperature surpasses the boiling point, a strong possibility exists for vapors and plasma formation. Consequently, an excessive amount of laser energy is absorbed by the produced vapors and plasma, thus impeding the deposition process.

Laser melting deposition is a 3D printing method usually studied for the manufacturing of machine parts in the industry. However, for the medical sector, although feasible, applications and actual products taking advantage of this technique are only scarcely reported. Therefore, in this study, Ti6Al4V orthopedic implants in the form of plates were 3D printed by laser melting deposition. Tuning of the laser power, scanning speed and powder feed rate was conducted, in order to obtain a continuous deposition after a single laser pass and to diminish unwanted blown powder, stuck in the vicinity of the printed elements. The fabrication of bone plates is presented in detail, putting emphasis on the scanning direction, which had a decisive role in the 3D printing resolution. The printed material was investigated by optical microscopy and was found to be dense, with no visible pores or cracks. The metallographic investigations and X-ray diffraction data exposed an unusual biphasic α+β structure. The energy dispersive X-ray spectroscopy revealed a composition very similar to the one of the starting powder material. The mapping of the surface showed a uniform distribution of elements, with no segregations or areas with deficient elemental distribution. The in vitro tests performed on the 3D printed Ti6Al4V samples in osteoblast-like cell cultures up to 7 days showed that the material deposited by laser melting is cytocompatible.

In this study, crack-free TiC/Ti composites with TiC content ranging from 0 to 15 wt.% were successfully fabricated using Direct Energy Deposition with a dual-feeder system that concomitantly delivered different amounts of both constituents into a high-power laser beam. The samples were investigated to evaluate the morphologies and distribution behavior of TiC. The microhardness values of the samples obtained under optimal processing conditions increased from 192 ± 5.3 HV_0.2 (pure Ti) to 300 ± 14.2 HV_0.2 (Ti + wt.% 15 TiC). Also, TiC has a significant impact on the Ti matrix, increasing the strength of TMCs up to 725 ± 5.4 MPa, while the elongation drastically decreased to 0.62 ± 0.04%. The wear rate is not proportionally affected by the rise content of TiC reinforcement; the hypoeutectic region of TMCs exhibited a wear rate of 2.45 mm³/N·m (Ti + wt.% 3 TiC) and a friction coefficient of 0.48 compared to the ones from the hypereutectic region, which measured a wear rate of 3.02 mm³/N·m (Ti + wt.% 15 TiC) and a friction coefficient of 0.63. The improved values of mechanical properties in the case of TMCs as compared to pure Ti are provided due to the solid solution strengthening of carbon and the fine grain strengthening. This work outlines a method for changing TiC morphologies to improve the hardness and tensile strength of TMCs fabricated starting from micro-scale powder.

Ti6Al4V cranial prostheses in the form of patterned meshes were 3D printed by selective laser melting in an argon environment; using a CO₂ laser source and micron-sized Ti6Al4V powder as the starting material. The size and shape of prostheses were chosen based on actual computer tomography images of patient skull fractures supplied in the framework of a collaboration with a neurosurgery clinic. After optimizations of scanning speed and laser parameters, the printed material was defect-free (as shown by metallographic analyses) and chemically homogeneous, without elemental segregation or depletion. The prostheses were coated by radio-frequency magnetron sputtering (RF-MS) with a bioactive thin layer of hydroxyapatite using a bioceramic powder derived from biogenic resources (Bio-HA). Initially amorphous, the films were converted to fully-crystalline form by applying a post-deposition thermal-treatment at 500 °C/1 h in air. The X-ray diffraction structural investigations indicated the phase purity of the deposited films composed solely of a hexagonal hydroxyapatite-like compound. On the other hand, the Fourier transform infrared spectroscopic investigations revealed that the biological carbonatation of the bone mineral phase was well-replicated in the case of crystallized Bio-HA RF-MS implant coatings. The in vitro acellular assays, performed in both the fully inorganic Kokubo’s simulated body fluid and the biomimetic organic–inorganic McCoy’s 5A cell culture medium up to 21 days, emphasized both the good resistance to degradation and the biomineralization capacity of the films. Further in vitro tests conducted in SaOs-2 osteoblast-like cells showed a positive proliferation rate on the Bio-HA RF-MS coating along with a good adhesion developed on the biomaterial surface by elongated membrane protrusions.

Laser Melting Deposition (LMD) is a metal printing technique that allows for the manufacturing of large objects by Directed Energy Deposition. Due to its versatility in variation of parameters, the possibility to use two or more materials, to create alloys in situ or produce multi-layer structures, LMD is still being scientifically researched and is still far from industrial maturity. The structural testing of obtained samples can be time consuming and solutions that can decrease the samples analysis time are constantly proposed in the scientific literature. In this manuscript we present a quality improvement study for obtaining defect-free bulk samples of Ti6Al4V under X-Ray Computed Tomography (XCT) by varying the hatch spacing and distance between planes. Based on information provided by XCT, the experimental conditions were changed until complete elimination of porosity. Information on the defects in the bulk of the samples by XCT was used for feedback during parameters tuning in view of complete removal of pores. The research time was reduced to days instead of weeks or months of samples preparation and analysis by destructive metallographic techniques.