The paper briefly describes major thermal spray techniques used to spray functionally graded coatings such as atmospheric plasma spraying, high velocity oxy-fuel spraying, suspension and solution precursor plasma spraying, and finally low and high pressure cold gas spray method. The examples of combined spray processes as well as some examples of post spray treatment including laser and high temperature treatments or mechanical one, are described. Then, the solid and liquid feedstocks used to spray and their properties are shortly discussed. The reviewed properties of functional coatings include: (i) mechanical (adhesion, toughness, hardness); (ii) physical (porosity, thermal conductivity and diffusivity, thermal expansion, photo-catalytic activity), and; (iii) bioactivity and simulated body fluid (SBF) corrosion. These properties are useful in present applications of functionally graded coatings as thermal barriers, the bioactive coatings in prostheses, photo-catalytic coatings in water treatment, coatings used in printing industry (anilox and corona rolls). Finally, some of the future possible fields of functional thermal sprayed coatings applications are discussed, e.g., to coat polymer substrates or to use the cheap technology of low pressure cold gas spray method instead of expensive technology of vacuum plasma spraying to obtain bond coatings.

Studies on bonding of aluminium alloys to steels are popular because these are structural materials widely used in a variety of industries. However, joining these dissimilar materials is difficult mainly because of the formation of brittle intermetallic compounds. This paper presents a study on welding aluminium to steel by resistance spot welding. Before the welding, steel surface was covered by cold spraying with the layer of aluminium, nickel and nickel–aluminium. This way, instead of the welding of dissimilar materials, the welding of aluminium to aluminium (or nickel) layer pre-deposited on the steel sample was performed. The feasibility of using interlayers for improving the welding of dissimilar materials was tested using SEM, EDX and XRD. Mechanical properties of welds were investigated by microhardness and shear strength tests. The results showed that the coating allowed to decrease hardness in the welding zone and to increase the shear strength of the weld.

In many industries, polymers are in great demand due to their low weight and good mechanical properties. However, films and coatings are sometimes applied to improve polymer surface properties. This work presents a study on the metallisation of polycarbonates using a low pressure cold spray (LPCS) method. Two types of commercial powders were selected for the deposition of coatings: (i) tin and (ii) aluminium. The coatings were applied (i) on an unmodified substrate and (ii) on a substrate with an interlayer, which enabled the formation of good adherent aluminium coatings. A light and scanning microscopy was used to analyse the microstructure of coatings. Electrical conductivity was determined using the four-probe method and is discussed in relation to the oxygen content. Moreover, bond strength and microhardness were investigated.