Aluminum alloys are the most important part of all shaped castings manufactured, especially in the aerospace and automotive industries. This work focuses on the corrosion properties of the heat-hardening aluminum alloys commonly used for production of automotive castings AlSi7Mg0.3 and on self-hardening AlZn10Si8Mg. Iron is a common impurity in aluminum cast alloy and its content increases by using secondary aluminum alloys. Therefore, experimental materials were developed, with chemical composition according to standards (primary alloys) and in states with an increasing content of Fe. The experimental aluminum alloys are briefly discussed in terms of their chemical composition, microstructure, mechanical properties and corrosion behavior. Corrosion properties were examined using three types of corrosion tests: exposure test, potentiodynamic tests, and Audi tests. Corrosion characteristics of materials were evaluated using stereo, optical and scanning electron microscopy, energy dispersive X-ray analysis, too. Correlation of pit initiation sites with microstructural features revealed the critical role of iron-rich phases, silicon particles and corresponding alloy matrix.
In this work, the quality of coatings prepared by plasma electrolytic oxidation (PEO) on an AZ31 magnesium alloy were evaluated. This was done by studying the effects of the chemical composition of phosphate-based process electrolytes in combination with different applied current densities on coating thickness, porosity, micro-cracking and corrosion resistance in 0.1 M NaCl. Both processing parameters were studied in four different levels. Mid-term corrosion resistance in 0.1 M NaCl was examined by electrochemical impedance spectroscopy and based on this, corrosion mechanisms were hypothesized. Results of performed experiments showed that the chosen processing parameters and electrolyte composition significantly influenced the morphology and corrosion performance of the prepared PEO coatings. The PEO coating prepared in an electrolyte with 12 g/L Na3PO4·12H2O and using an applied current density 0.05 A/cm2 reached the highest value of polarization resistance. This was more than 11 times higher when compared to the uncoated counterpart.
This article provides an overview of the influence of welding parameters and filler material on changes in the heat-affected zone (HAZ) of thermo-mechanically controlled processed (TMCP) steel welded joints. The research focused on evaluating the effect of heat input and cooling rate on the width of the soft zone, which significantly affects the mechanical properties of welded joints. The negative effect of the soft zone is more pronounced as the thickness of the material decreases. Therefore, the object of this research was a 3-mm-thick sheet of S960MC steel welded by gas metal arc welding (GMAW) and metal-cored arc welding (MCAW) technology. Variable welding parameters were reflected in different heat input and cooling rate values, which led to a change in the properties of the HAZ and thus the mechanical properties of the welded joints. The changes in the HAZ were analyzed by microscopic analysis and mechanical testing. The measured results showed a significant effect of heat input on the cooling rate, which considerably affected the width of the soft zone in the HAZ and thus the overall mechanical properties of the welded joints.
High strength low alloy (HSLA) steels exhibit many outstanding properties for industrial applications but suffer from unsatisfactory corrosion resistance in the presence of aggressive chlorides. Phosphate coatings are widely used on the surface of steels to improve their corrosion properties. This paper evaluates the effect of a manganese phosphate coating prepared after various mechanical surface treatments on the electrochemical corrosion characteristics of S355J2 steel in 0.1 M NaCl electrolyte simulating aggressive sea atmosphere. The manganese phosphate coating was created in a solution containing H3PO4, MnO2, dissolved low carbon steel wool, and demineralised H2O. Scanning electron microscopy (SEM) was used for surface morphology observation supported by energy-dispersive X-ray analysis (EDX). The electrochemical corrosion characteristics were assessed by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PD) measurements in the solution of 0.1 M NaCl. Method of equivalent circuits and Tafel-extrapolation were used for the analysis of the obtained results. Performed experiments and analysis showed that the morphological and corrosion properties of the surface with manganese phosphate are negatively influenced by sandblasting surface pretreatment.
The severe shot peening process was applied to the notched specimens from an AW 7075 alloy with the aim to improve fatigue endurance in the very-high cycle fatigue region. To reveal the stress state in the notch vicinity, finite element analysis was performed, simulating the conditions of the used 20 kHz ultrasonic fatigue loading. Modified surface characteristics by the severe shot peening process were analyzed in terms of residual stress distribution measured by X-ray diffraction methods and near-surface microstructural observations by scanning electron microscopy. The applied severe shot peening increased the fatigue limit by 11%; however, the positive effect was recorded only for the loading amplitudes corresponding to the fatigue lifetimes in the range 107–109 cycles. At higher loading amplitudes, the fatigue properties tended to decrease, most likely due to accelerated fatigue crack initiation on the surface damage features created by the peening process and also by rapid residual stress relaxation.
The contribution deals with the preparation of the dicalcium phosphate-dihydrate (DCPD) coating on ZW3 magnesium alloy surface. The coating was prepared using large amplitude sinusoidal voltammetry (LASV) electrodeposition technique in water solution of 0.1M Ca(NO3)2.4H2O + 0.06M NH4HPO4 + 10 ml.dm-3of 50 vol.% H2O2. The influence of the DCPD coating on electrochemical characteristics was examined using potentiodynamic polarization (PD) tests and electrochemical impedance spectroscopy (EIS) at the temperature 22 ± 2 °C in 0.1M NaCl. The obtained PD curves were analysed using Tafel extrapolation method and the data obtained by EIS measurements in a form of Nyquist plots were analysed quantitatively by equivalent circuit method. The results showed the increase of corrosion resistance after application of DCPD coating on ZW3 Mg alloy in sodium chloride solution.