Chemical composition and morphological properties of Norway spruce wood and bark were evaluated. The extractives, cellulose, hemicelluloses, and lignin contents were determined by wet chemistry methods. The dimensional characteristics of the fibers (length and width) were measured by Fiber Tester. The results of the chemical analysis of wood and bark show the differences between the trunk and top part, as well as in the different heights of the trunk and in the cross section of the trunk. The biggest changes were noticed between bark trunk and bark top. The bark top contains 10% more of extractives and 9.5% less of lignin. Fiber length and width depends on the part of the tree, while the average of these properties are larger depending on height. Both wood and bark from the trunk contains a higher content of fines (fibers 0.5 mm) compared to the top. During storage, it reached a decrease of extractives mainly in bark. Wood from the trunk retained very good durability in terms of chemical composition during the storage. In view of the morphological characteristics, it occurred to decrease both average fibers length and width in wood and bark.

Effect of Thermal Treatment on the Chemical, Physical, and Mechanical Properties of Pedunculate Oak (Quercus robur L.) Wood

Waste tires (granulate) and selected plastics from the automotive industry were evaluated by using the tertiary (pyrolysis) and quaternary (calorimetry) recovering. Pyrolysis is proving to be an environmentally friendly alternative to incineration and inefficient landfilling. Currently, the main challenges for pyrolysis of plastic waste are unavailability and inconsistent quality of feedstock, inefficient and hence costly sorting, and last but not least insufficient regulations around plastic waste management. Waste plastics and tire materials were characterized by TG/DTG analysis, Py-GC/MS analysis and calorimetry. TG analysis of the investigated materials gives the typical decomposition curves of synthetic polymers. The tested samples had the highest rate of weight loss process in the temperature range from 375 °C to 480 °C. Analytical pyrolysis of the tested polymers provided information on a wide variety of organic compounds that were released upon thermal loading of these materials without access to oxygen. Analytical pyrolysis offers valuable information on the spectrum of degradation products and their potential uses. Based on the results of calorimetry, it can be stated that the determined calorific value of selected plastic and rubber materials was ranging from 26.261 to 45.245 MJ/kg depending on the ash content and its composition.

This research work aims to investigate the effects of thermal modification and wood cutting direction (transverse, radial and tangential) on the content of extractives, lignin, cellulose, and hemicelluloses, and on the thermal conductivity of Norway spruce (Picea abies L.) wood. Samples were thermally modified for 3, 6, and 9 h at temperatures of 160°C, 180°C, and 200°C in the oxidizing atmosphere with natural convection. The extractives, lignin, cellulose, and holocellulose contents were determined by wet chemistry methods, the structural changes were evaluated by using Fourier-transform infrared spectroscopy (FTIR). The highest relative content of extractives was determined at the temperature of 200°C and a thermal modification duration of 9 h. The lignin content decreased at the temperature of 160°C and increased at higher temperatures due to the formation of pseudo-lignin. The cellulose content increased, and hemicellulose content decreased with the increased temperature and thermal modification duration. FTIR analyses revealed changes mainly at the temperature of 200°C, primarily a decrease in the intensities of the characteristic absorption bands of lignin due to degradation reactions. Markedly, density and thermal conductivity decreased mostly due to depolymerization of hemicelluloses. Regarding the thermal conductivity, a slightly higher decrease in transversal and tangential sections was determined.

Particleboards containing waste rubber (tires and mixtures of isolators and carpets) filler were evaluated from the point of view of its flammability. The assessment of the utilization of these composites in the construction industry was analyzed through the determination of their spontaneous ignition temperatures, mass burning rate and calorific value. Based on the results of spontaneous ignition temperatures, similar values between particleboards and particleboards containing 10%, 15% and 20% of waste tires were obtained. The average time was from 298 s to 309 s and the average temperature was from 428.1 °C to 431.7 °C. For the mass burning rate, there were similar results between particleboards and particleboards containing 10% of waste tires and waste rubber. The time to initiation was 34 s and the time to reaching a maximal burning rate was from 66 s to 68 s. The calorimetry results showed similar properties for the calorimetric value and ash content in particleboards and particleboards containing 10% of waste tires and waste rubber. The calorific value was from 18.4 MJ·kg⁻¹ to 19.7 MJ·kg⁻¹ and the ash content from 0.5% to 2.9%.

The paper assesses the influence of the heat flux on spruce wood (Picea abies L.) behavior. The heat flux was performed at 15, 20, 25, and 30 kW·m⁻². The fire-technical properties, such as the mass burning rate, charring thickness, charring rate, as well as the chemical composition (contents of the extractives, lignin, cellulose, holocellulose), of wood were determined. The highest burning rate of spruce wood of 0.32%·s⁻¹ was reached at the heat flux of 30 kW·m⁻². The charring rate ranged from 1.004 mm·min⁻¹ (15 kW·m⁻²) to 2.016 mm·min⁻¹ (30 kW·m⁻²). The proposed model of the charring process of spruce wood in time and appropriate thickness as a selected parameter is applicable in validation of the results of computer fire models in the design of fire protection of wooden buildings. The decrease in the holocellulose content mostly caused by the degradation of hemicelluloses was observed during thermal loading. The biggest decrease in hemicelluloses (24.94%) was recorded in samples loaded at 30 kW·m⁻². The contents of cellulose increased due to the structural changes (carbonization and crosslinking), the content of lignin increased as well due to its higher thermal stability compared to saccharides, as well as the resulting lignin condensation.