Using Kraft lignin, bio-based adhesives have been increasingly studied to replace those petrochemical-based solutions, due to low cost, easy availability and the potential for biodegradability of this biomaterial. In this study, lignin-based phenol-formaldehyde (LPF) resins were synthesized using commercial Eucalypt Kraft Lignin (EKL), purified at 95%, as a phenol substitute in different proportions of 10%, 20%, 30% and 50%. The properties of bio-based phenol formaldehyde (BPF) synthesized resin were compared with phenol-formaldehyde resin (PF) used for control sampling. The results indicated that viscosity, gel time and solid contents increased with the addition of pure EKL. The shear strength test of glue line was studied according to American Society for Testing and Materials (ASTM), and BPF-based results were superior to samples bonded with the PF as a control sample, being suitable for structural purposes. Changes in the curing behavior of different resins were analyzed by Differential Scanning Calorimetry (DSC), and sample comparison indicated that the curing of the LPF resin occurred at lower temperatures than the PF. The addition of EKL in PF reduced its thermal stability compared to traditional resin formulation, resulting in a lower decomposition temperature and a smaller amount of carbonaceous residues.

Plywood is widely used in civil construction. Due to the importance of preservation and gluing in bio-composites, this study compares the influence of a chemical treatment with CCA (chromated-copper-arsenate) on Pinus taeda L. wood veneers to produce two plywood types using phenol-formaldehyde (PF) and castor oil-based polyurethane (PU). Four different treatments were performed to analyze both varieties’ physical and mechanical properties. As a result, an improvement in the properties of the treated panels was observed. Lower moisture contents and better interactions caused by less thickness swelling and water absorption were identified in the PU-based plywoods. The treatment with CCA was efficient, improving these properties when they were compared to the reference panels. Most treatments evidenced increases in the modulus of elasticity and modulus of rupture for both adhesives when the CCA treatment was applied to the veneers. Comparing the resins, the PF showed the best values of modulus of elasticity. All treatments met the requirements defined by the Brazilian standard document for the glue line shear.

The present study aimed to evaluate the feasibility of developing low-cost N- and Fe-doped TiO₂ photocatalysts for investigating the mineralization of 2,4-dimethylaniline (2,4-DMA). With a single anatase phase, the photocatalysts showed high thermal stability with mass losses of less than 2%. The predominant oxidative state is Ti⁴⁺, but there is presence of Ti³⁺ associated with oxygen vacancies. In materials with N, doping was interstitial in the NH₃/NH⁴⁺ form and for doping with Fe, there was a presence of Fe-Ti bonds (indicating substitutional occupations). With an improved band gap energy from 3.16 eV to 2.82 eV the photoactivity of the photocatalysts was validated with an 18 W UVA lamp (340–415 nm) with a flux of 8.23 × 10⁻⁶ Einstein s⁻¹. With a size of only 14.45 nm and a surface area of 84.73 m² g⁻¹, the photocatalyst doped with 0.0125% Fe mineralized 92% of the 2,4-DMA in just 180 min. While the 3% N photocatalyst with 12.27 nm had similar performance at only 360 min. Factors such as high surface area, mesoporous structure and improved E_bg, and absence of Fe peak in XPS analysis indicate that doping with 0.0125% Fe caused a modification in TiO₂ structure.

Carbon fiber-reinforced polymer (CFRP) sheets have been used to reinforce cross-laminated timber (CLT)–concrete systems in recent years. The existing studies have indicated that the use of CFRP rebars as shear connectors in CLT–concrete panels can improve the structural performance of these elements. However, the application and understanding of CFRP rebars as shear connectors still need to be improved, since comprehensive studies on the subject are not available. Therefore, this research aimed to evaluate the structural performance of CLT–concrete panels with CFRP rebars as shear connectors through finite element (FE) numerical simulation. A parametric study was conducted, varying the connector material, the number of CLT layers, the connector insertion angle, and the connector embedment length. According to the results, panels with CFRP connectors showed a higher maximum load, bending strength, and maximum bending moment than panels with steel connectors. The regression models revealed that the parameters analyzed explained between 80.2% and 99.9% of the variability in the mechanical properties under investigation. The high explanatory power (R²) of some regression models in this study underscores the robustness of the models. The number of CLT layers and the connector material were the most significant parameters for the panels’ maximum load, displacement at the maximum load, ductility, bending strength, and maximum bending moment. The number of CLT layers and the connector insertion angle were the most significant parameters for the panels’ effective bending stiffness. This research highlights the importance of studies on CLT–concrete composites and the need to develop equations to estimate their behavior accurately. Moreover, numerical simulations have proven very valuable, providing results comparable to laboratory results.

Codes of practices and standards for products and activities are available regulations for global sectors, although they are dedicated to national scopes such as civil construction in Brazil. These regulations align with industry compliance as they establish mandatory or voluntary issues. Brazilian developers must properly regard construction regulations, which mostly dedicated to concrete and steel buildings but rarely to timber buildings. Through construction regulations, the production of timber buildings can become more standardized and scalable to ensure the steady quality of finished products. From this perspective, this paper evaluated Brazil’s timber housing production sector’s utilization and access to procedures, standards, guidelines, certifications, and seals. A standardized questionnaire was designed and refined to analyze this local perspective. Face-to-face interviews with sampled companies were conducted using a randomized sampling procedure. The margin of error was obtained using significant sampling of this sector. The findings evinced that most Brazilian developers underuse timber building regulations in their production and management practices and still need to familiarize themselves with this important subject. The codes must establish requirements for each timber construction technique to represent different technologies and also specify particularities and added performances to suit varied projects.

Simultaneous hydrogen fuel and value-added chemical production from renewable resources is a key strategy in sustainable catalysis. This work presents a novel strategy employing metal–organic frameworks (MOFs) as precursors for synthesizing advanced titanium dioxide (TiO₂) photocatalysts with enhanced structural and optical properties. Two photocatalysts, M-BDC and M-2,5PDC, were synthesized via controlled calcination of MIL-125(Ti) using terephthalic and 2,5-pyridinedicarboxylic acids, respectively. Characterization confirmed the formation of mixed anatase/rutile TiO₂ phases with mesoporous structures. Notably, nitrogen incorporation in M-2,5PDC reduced the optical band gap to 2.94 eV compared with 3.08 eV for M-BDC, enhancing visible-light absorption. Photocatalytic experiments conducted at near-neutral pH (6.0) demonstrated effective simultaneous glycerol oxidation and hydrogen evolution without the use of alkaline additives. M-BDC achieved 30% glycerol conversion with 78.85% selectivity toward dihydroxyacetone and 21.15% toward glyceraldehyde, while M-2,5PDC exhibited selectivities of 71.55% and 28.45%, respectively. Glycerol underwent partial oxidation without complete mineralization, generating high-value products in parallel with hydrogen production. Both catalysts displayed excellent reuse stability across three consecutive cycles, with M-BDC showing enhanced dihydroxyacetone selectivity (78.85% to 84.42% between cycles). This MOF-derived TiO₂ platform integrates controlled synthesis, near-neutral pH operation, high selectivity, and catalytic stability, thereby establishing a viable strategy for the simultaneous production of clean fuel and value-added chemicals from renewable resources.