Problems with increasing heavy metal contents in natural waters are becoming a global issue. At the same time, improved methods for water treatment are becoming increasingly important. In this context, natural zeolites can be used to purify polluted water. In this paper, we investigated how the adsorption capacity of natural zeolites can be improved. Natural zeolites from the Shankanay district, Almaty, Kazakhstan, were used as adsorbent material for experiments on improving the water treatment of heavy metals. We found that the adsorption capacity for heavy metals was increased greatly by thermal activation using furnace treatment. The optimal thermal activation condition was about 550 °C for a duration of 2 h. However, the improved adsorption capacity for different heavy metals varied depending on the heat treatment temperature. Adsorption by the heat-treated zeolites at a temperature of 550 °C was 87% for nickel, 99% for copper and cadmium, and 100% for lead. Adsorption by heat-treated zeolites at a temperature of 500 °C was 78% for nickel, 98% for copper, 83% for cadmium, and 88% for lead. The residual concentration of heavy metals in the filtered water did not exceed the maximum permissible concentrations for drinking purposes. In all experiments, intense adsorption took place during the first 10 min representing 35 to 61% of the metal ions in the water. Adsorption properties were verified using adsorption capacity (BET), IR spectroscopy, and scanning electron microscopy. The study shows that modified Shankanay natural zeolites have great potential as a low-cost adsorbent material for purifying water from heavy metals.

Providing safe drinking water to people in developing countries is an urgent worldwide water problem and a main issue in the UN Sustainable Development Goals. One of the most efficient and cheapest methods to attain these goals is to promote the use of slow sand filters. This review shows that slow sand filters can efficiently provide safe drinking water to people living in rural communities not served by a central water supply. Probably, the most important aspect of SSF for developing and less-developed countries is its function as a biological filter. WASH problems mainly relate to the spread of viruses, bacteria, and parasites. The surface and shallow groundwater in developing countries around urban areas and settlements are often polluted by domestic wastewater containing these microbes and nutrients. Thus, SSF’s function is to treat raw water in the form of diluted wastewater where high temperature and access to nutrients probably mean a high growth rate of microbes and algae but probably also high predation and high efficiency of the SSF. However, factors that may adversely affect the removal of microbiological constituents are mainly low temperature, high and intermittent flow rates, reduced sand depth, filter immaturity, and various filter amendments. Further research is thus needed in these areas, specifically for developing countries.

Purpose. A methodology development for predicting the geomechanical situation when mining an ore deposit with steep-dipping layers, taking into account the uncertainty in determining the rock properties, which is a consequence of the rock mass heterogeneity. Methods. The assessment of the open-pit wall stability is based on a combination of numerical simulation of the rock stress-strain state (SSS) and probabilistic analysis. The finite element method is used to determine the changes in the SSS that occur at various stages of mining operations due to design changes in the overall open-pit slope angle. The elastic-plastic model of the medium and the Mohr-Coulomb failure criterion are implemented in the codes of the 3D finite element analysis program RS3 (Rocscience). Stochastic simulation is used to assess random risks associated with natural object state variations. Findings. The distribution of maximum shear strains, which localizes the real or potential sliding surfaces in the open-pit wall at various stages of ore mining, has been identified. Based on the Shear Strength Reduction procedure, the open-pit wall Strength Reduction Factor (SRF) has been determined. The probabilities of open-pit wall stability loss, as well as the decrease in the strength reduction factor below the standard level at all stages of the ore body mining, have been revealed. Originality. For the first time, for real mining-geological conditions of a deep ore open pit, the dependence of the strength reduction factor on the overall wall slope angle, which changes during mining of each steep layer, has been determined. For each stage of mining operations, for the first time, the probability of a decrease in the open-pit wall stability below the standard level has been determined based on stochastic simulation. Practical implications. The ratio between the open-pit contour characteristic (overall slope angle) and the probabilistic safety factor is the basis for practical solutions to ensure the efficiency and safety of mining at various stages of friable and hard overburden excavation, ore extraction, as well as for the subsequent optimization of the open-pit design contours.

This work is devoted to the study of the radiation damage kinetics and subsequent embrittlement of the near-surface layer of SiC ceramics subjected to irradiation with low-energy He²⁺ ions. Interest in these types of ceramics is due to their great prospects for use as structural materials for nuclear power, as well as for use in the creation of protective structures for long-term storage of spent nuclear fuel. During the study, the dependences of changes in the structural, mechanical, strength, and morphological characteristics of SiC ceramics depending on irradiation fluence were obtained. It has been established that the greatest changes in the strength properties are associated with the dominance of the crystal lattice swelling effect in the structure due to an increase in the concentration of implanted helium, and its further agglomeration with the formation of vacancy complexes of the He-V type. A model for changing the structural properties of ceramics irradiated with low-energy He²⁺ ions based on the change in the contributions of the dislocation density concentration, anisotropic distortion of the crystal lattice, and the effect of swelling as a result of implantation is proposed.

The possibility of producing cement clinker using low-energy, resource-saving technologies is studied. The composition of industrial waste for low-energy-intensive production of Portland cement clinker at factories in Southern Kazakhstan is analyzed. The possibility of replacing the deficient iron-containing corrective additive with “Waelz clinker for zinc ores” is shown. “Waeltz clinker from zinc ores” as part of the raw material charge performs several tasks: it is a ferrous corrective additive, works as a mineralizer for clinker formation processes, introduces coal into the charge and allows one to reduce the consumption of natural fuel. The processes of burning raw mixtures, wholly or partially consisting of industrial waste, are completed at 1350 °C. This reduces the consumption of main burner fuel for clinker burning and reduces CO₂ emissions into the atmosphere. High-quality cement clinker is obtained based on raw material mixtures with Waeltz clinker from zinc ores from the Achisai Metallurgical Plant, phosphorus slag, coal mining waste from Lenger mines and sodium fluoride. The phase composition and microstructure of low-energy clinkers are revealed. Involving industrial waste in raw material circulation will reduce environmental pollution and improve the environment.

New experimental results have been obtained on the behavior of arsenic and other associated metals (Re and others) under conditions of oxidative and reductive sintering. It has been established that the extraction of arsenic strongly depends on the process temperature during oxidative sintering. The extraction of arsenic into dust media at 873 K is 50% and rhenium is 88–90%. The effect of excess air on the extraction of arsenic and rhenium into dust was studied: the higher the excess air coefficient, the more complete the extraction of arsenic and rhenium into the dust. The obtained data indicate that achieving a high level of arsenic extraction from the initial product is not possible during oxidative sintering. The best arsenic removal results were reached under the conditions of reductive sintering of initial material by natural gas. The extraction of arsenic into dust at 823 K was 88%, and at 1373 K arsenic is almost completely converted into dust. Obtained new experimental results have a fundamental importance for the selection and organization of a comprehensive technology for the processing complex in composition refractory gold-copper-arsenic-bearing products.