This review explores the impact of various additives on the mechanical properties of polylactic acid (PLA) filaments used in Fused Deposition Modeling (FDM) 3D printing. While PLA is favored for its biodegradability and ease of use, its inherent limitations in strength and heat resistance necessitate enhancements through additives. The impact of natural and synthetic fibers, inorganic particles, and nanomaterials on the mechanical properties, printability, and overall functionality of PLA composites was examined, indicating that fiber reinforcements, such as carbon and glass fibers, significantly enhance tensile strength and stiffness, while natural fibers contribute to sustainability but may compromise mechanical stability. Additionally, the inclusion of inorganic particulate fillers like calcium carbonate improves dimensional stability and printability, although larger particles can lead to agglomeration issues. The study highlights the potential for improved performance in specific applications while acknowledging the need for further investigation into optimal formulations and processing conditions.

Material Extrusion-Based Additive Manufacturing Process (ME-AMP) via Fused Filament Fabrication (FFF) offers a higher geometric flexibility than conventional technologies to fabricate thermoplastic lightweight sandwich structures. This study used polylactic acid/polyhydroxyalkanoate (PLA/PHA) biodegradable material and a 3D printer to manufacture lightweight sandwich structures with honeycomb, diamond-celled and corrugated core shapes as a single part. In this paper, compression, three-point bending and tensile tests were performed to evaluate the performance of lightweight sandwich structures with different core topologies. In addition, the main failure modes of the sandwich structures subjected to mechanical tests were evaluated. The main failure modes that were observed from mechanical tests of the sandwich structure were the following: face yielding, face wrinkling, core/skin debonding. Elasto-plastic finite element analysis allowed predicting the global behavior of the structure and stressing distribution in the elements of lightweight sandwich structures. The comparison between the results of bending experiments and finite element analyses indicated acceptable similarity in terms of failure behavior and force reactions. Finally, the three honeycomb, diamond-celled and corrugated core typologies were used in the leading edge of the wing and were impact tested and the results created favorable premises for using such structures on aircraft models and helicopter blade structures.

This paper discusses the structure morphology and the thermal and swelling behavior of physically crosslinked hydrogels, obtained from applying four successive freezing–thawing cycles to poly (vinyl alcohol) blended with various amounts of κ-carrageenan. The addition of carrageenan in a weight ratio of 0.5 determines a twofold increase in the swelling degree and the early diffusion coefficients of the hydrogels when immersed in distilled water, due to a decrease in the crystallinity of the polymer matrix. The diffusion of water into the polymer matrix could be considered as a relaxation-controlled transport (anomalous diffusion). The presence of the sulfate groups determines an increased affinity of the hydrogels towards crystal violet cationic dye. A maximum physisorption capacity of up to 121.4 mg/g for this dye was attained at equilibrium.

In three-dimensional (3D) printing, one of the main parameters influencing the properties of 3D-printed materials is the infill density (ID). This paper presents the influence of ID on the microstructure, mechanical, and thermal properties of carbon fiber-reinforced composites, commercially available, manufactured by the Fused Filament Fabrication (FFF) process. The samples were manufactured using FFF by varying the infill density (25%, 50%, 75%, and 100%) and were subjected to tensile tests, three-point bending, and thermal analyses by Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). It was shown that the samples with 100% ID had the highest values of both tensile, 90.8 MPa, and flexural strengths, 114 MPa, while those with 25% ID had the lowest values of 56.4 MPa and 62.2 MPa, respectively. For samples with infill densities of 25% and 50%, the differences between the maximum tensile and flexural strengths were small; therefore, if the operating conditions of the components allow, a 25% infill density could be used instead of 50%. After DSC analysis, it was found that the variation in the ID percentage determined the change in the glass transition temperature from 49.6 °C, for the samples with 25% ID, to 32.9 °C, for those with 100% ID. TGA results showed that the samples with IDs of 75% and 100% recorded lower temperatures of onset degradation (approximately 344.75 °C) than those with infill densities of 25% and 50% (348.5 °C, and 349.6 °C, respectively).

Additive manufacturing (AM) is used in many fields and is a method used to replace wood components or wood-jointed furniture components in the furniture industry. Replacing wood joints by 3D printed connectors would be an advantage, considering the fact that during the process of assembling furniture, the execution technology of the joints is difficult, time-consuming, and labor-intensive. Advanced technology of AM applied in furniture manufacturing helps the designers to create new concepts of product design, with no limits of shape, number of joints, color, or size. The diversity of 3D printers and AM technologies provides the selection of materials in relation with the applicability of the 3D printed object. In this respect, the objective of the present research is to design a 3D printed connector to be used for jointing three chair components, namely the leg and two stretchers made from larch (Larix decidua Mill.) wood, and to use reinforced polylactic acid (PLA) fiberglass (20 wt. %) filament for 3D printing this connector using AM with fused filament fabrication (FFF) technology. The design of the connector, the possibility of using this type of material, and the deposition method of filament were investigated in this research. For this purpose, several evaluation methods were applied: microscopic investigation with 50×, 100×, and 200× magnifications, both of the filament and of the 3D printed connector; mechanical testing of corner joint formed with the help of connector between chair leg and the two stretchers; and a microscopic investigation of the connectors’ defects that occurred after applying the compression and tensile loads on the diagonal direction of the L-type joint. The microscopic investigation of the composite filament revealed the agglomerations of glass fibers into the core matrix and areas where the distribution of the reinforcements was poor. The heterogeneous structure of the filament and the defects highlighted in the 3D printed connectors by the microscopic investigation contributed to the mechanical behavior of L-type connecting joints. The bending moments resulting from compression and tensile tests of the 3D printed connectors were compared to the results recorded after testing, under the same conditions, the normal mortise–tenon joint used to assemble the abovementioned chair components. The larch wood strength influenced the mechanical results and the conclusions of the microscopic investigations, as well as the analysis of the broken connectors after testing recommended the change of connector design and filament deposition direction.