This article examines electrochemical carbon monoxide (CO) sensors used as mobile devices by rescue and firefighting units in Poland. The conducted research indicates that the presence of chlorine (Cl₂), ammonia (NH₃), hydrogen sulfide (H₂S), hydrogen chloride (HCl), hydrogen cyanide (HCN), nitrogen (IV) oxide (NO₂), and sulfur (IV) oxide (SO₂) in the atmosphere does not affect the functioning of the electrochemical CO sensor. In the case of this sensor, there was a significant cross effect in relation to hydrogen (H₂). It was found that the time and manner of using the sensor affects the behavior in relation to H₂. Such a relationship was not recorded for CO. Measurements in a mixture of CO and H₂ confirm the effect of hydrogen on the changes taking place inside the sensor. Independently of the ratio of H₂ to CO, readings of CO were flawed. All analyses showed a significant difference between the electrochemical CO sensor readings and the expected values. Only in experiments with a 1:3 mixture of CO and H₂ was the relative error less than 15%. The relative error in the analyzed concentration range for a sensor with an additional compensation electrode ranged from 7% to 38%; for a sensor without this electrode, it ranged from 23% to 55%. It was ascertained that in the cases of measurements for tests carried out at higher concentrations of H₂ in relation to CO, a sensor with an additional electrode is significantly better (more accurate) than a sensor without such an electrode. Differences at the significance level p = 0.01 for measurements made in the CO:H₂ mixture at a ratio of 1:3 were ascertained.

Fires in landfills, where used plastic packaging waste is discarded, have shown how great a fire hazard these types of materials pose. In this study, the course of thermo-oxidation of samples made of polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET) based plastics was determined. Based on an analysis of the dissociation energy of bonds between atoms in a polymer molecule, the mechanisms responsible for the character and course of degradation were observed. It was found that the degradation rate of PP and PS could be a result of the stability of C-H bonds on the tertiary carbon atom. In the case of PS, due to facilitated intramolecular hydrogen transfer, stabilization of hydroperoxide, and formation of a stable tertiary alcohol molecule, the onset of degradation is shifted towards higher temperatures than in the case of PP. Notably, the PP fragmentation occurs to a greater extent due to the easier course of β-scission. In addition, it was found that during a fire, the least amount of heat would be generated by thermo-oxidation of PS-based plastics. This is a result of the formation of a styrene molecule during decomposition that, due to the high stability of bonds in the aromatic ring, escapes from the combustion zone without oxidation. It has been proven that the greatest thermal effect accompanies PET decomposition, during which a phenyl radical is produced, where the C-H bonds break more easily in comparison with the bonds of an intact ring.

The publication presents the results of a field test of 2–4 min releases of 96% LNG from a road tanker designed to carry the gas. The release was performed at a pressure of 5.9–6.1 atm at a discharge rate of 1.67–1.78 kg/s from a height of 0.75 m under class B conditions of atmospheric stability. Comparison of the obtained experimental results of the maximum concentrations and the simulation carried out with the EFFECS (11.2.0) software showed that the Gaussian gas model better describes the gas cloud propagation at most control points at this release intensity than the dense gas model. The dense gas model gave only slightly better results along the cloud propagation axis at close distances, not exceeding 25/30 m at ground level. It is shown that concentrations between 71% and 110% LEL are observed at the cloud visibility limit. The maximum value of the temperature drop, in the release axis, at a distance of 4 m amounts to ∆T_max = 93.3 °C. This indicates that the cloud of the released LNG is almost entirely in the vapour state already in the short distance from the point of release, due to the turbulent outflow of the pressurised gas.

The article examined selected individual protection used during rescue and fire-extinguishing activities. Fire helmet and special shoes were examined under conditions resembling the operational conditions of LNG gases. The assessment of the equipment consumption was based on strength tests. The main threats come from thermal and mechanical factors. Therefore, firefighters must properly protect their head and legs. At −80 °C, the energy of the impact force of the beater in the headache was, 12.4 J and 15.1 J for points P1 and P2, respectively. The studies showed that cooling the chamber to −80 °C adversely affected the structure of the fire helmet exposed to impact Dynamic. Research work was carried out as part of the Research and Development project No. DOB-BIO9/15/02/2018.