Pollution from dye containing wastewater leads to a variety of environmental problems, which can destroy plant life and eco-systems. This study reports development of a seaweed-based biochar as an adsorbent material for efficient adsorption of methylene blue (MB) dye from synthetic wastewater. The Eucheuma cottonii seaweed biochar was developed through pyrolysis using a tube furnace with N₂ gas, and the properties were later improved by sulfuric acid treatment. The adsorption studies were conducted in a batch experimental setup under initial methylene blue concentrations of 50 to 200 mg/L, solution pH of 2 to 10, and temperature of 25 to 75 °C. The characterization results show that the developed biochar had a mesoporous pore morphology. The adsorbent possessed the surface area, pore size, and pore volume of 640 m²/g, 2.32 nm, and 0.54 cm³/g, respectively. An adsorption test for 200 mg/L of initial methylene blue at pH 4 showed the best performance. The adsorption data of the seaweed-based biochar followed the Langmuir isotherm adsorption model and the pseudo-second-order kinetic model, with the corresponding R² of 0.994 and 0.995. The maximum adsorption capacity of methylene blue using the developed seaweed‑based biochar was 133.33 mg/g. The adsorption followed the chemisorption mechanism, which occurred via the formation of a monolayer of methylene blue dye on the seaweed-based biochar surface. The adsorption performance of the produced seaweed biochar is comparable to that of other commercial adsorbents, suggesting its potential for large-scale applications.

Oily-biological sludge (OBS) generated from petroleum refineries has high toxicity. Therefore, it needs an appropriate disposal method to reduce the negative impacts on the environment. The anaerobic co-digestion process is an effective method that manages and converts organic waste to energy. For effective anaerobic digestion, a co-substrate would be required to provide a suitable environment for anaerobic bacteria. In oily-biological sludge, the carbon/nitrogen (C/N) ratio and volatile solids (VS) content are very low. Therefore, it needs to be digested with organic waste that has a high C/N ratio and high VS content. This study investigates the use of sugarcane bagasse (SB) as an effective co-substrate due to its high C/N ratio and high VS content to improve the anaerobic co-digestion process with oily-biological sludge. The sugarcane bagasse also helps to delay the toxicity effect of the methane bacteria. Batch anaerobic co-digestion of oily-biological sludge was conducted with sugarcane bagasse as a co-substrate in twelve reactors with two-liter capacity, each under mesophilic conditions. The interaction effect of a C/N ratio of 20-30 and a VS co-substrate/VS inoculum ratio of 0.06-0.18 on the methane yield (mL CH₄/g VS_removed) was investigated. Before the anaerobic digestion, thermochemical pre-treatment of the inoculum and co-substrate was conducted using sodium hydroxide to balance their acidic nature and provide a suitable pH environment for methane bacteria. Design and optimization for the mixing ratios were carried out by central composite design-response surface methodology (CCD-RSM). The highest predicted methane yield was found to be 63.52 mL CH₄/g VS_removed, under optimum conditions (C/N ratio of 30 and co-substrate/inoculum ratio of 0.18).

Development of strategies for removing heavy metals from aquatic environments is in high demand. Cadmium is one of the most dangerous metals in the environment, even under extremely low quantities. In this study, kenaf and magnetic biochar composite were prepared for the adsorption of Cd²⁺. The synthesized biochar was characterized using (a vibrating-sample magnetometer VSM), Scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). The adsorption batch study was carried out to investigate the influence of pH, kinetics, isotherm, and thermodynamics on Cd²⁺ adsorption. The characterization results demonstrated that the biochar contained iron particles that help in improving the textural properties (i.e., surface area and pore volume), increasing the number of oxygen-containing groups, and forming inner-sphere complexes with oxygen-containing groups. The adsorption study results show that optimum adsorption was achieved under pH 5–6. An increase in initial ion concentration and solution temperature resulted in increased adsorption capacity. Surface modification of biochar using iron oxide for imposing magnetic property allowed for easy separation by external magnet and regeneration. The magnetic biochar composite also showed a higher affinity to Cd²⁺ than the pristine biochar. The adsorption data fit well with the pseudo-second-order and the Langmuir isotherm, with the maximum adsorption capacity of 47.90 mg/g.

Man-made organic waste leads to the rapid proliferation of pollution around the globe. Effective bio-waste management can help to reduce the adverse effects of organic waste while contributing to the circular economy at the same time. The toxic oily-biological sludge generated from oil refineries’ wastewater treatment plants is a potential source for biogas energy recovery via anaerobic digestion. However, the oily-biological sludge’s carbon/nitrogen (C/N) ratio is lower than the ideal 20–30 ratio required by anaerobic digestion technology for biogas production. Sugarcane bagasse can be digested as a high C/N co-substrate while the oily-biological sludge acts as a substrate and inoculum to improve biogas production. In this study, the best C/N with co-substrate volatile solids (VS)/inoculum VS ratios for the co-digestion process of mixtures were determined empirically through batch experiments at temperatures of 35–37 °C, pH (6–8) and 60 rpm mixing. The raw materials were pre-treated mechanically and thermo-chemically to further enhance the digestibility. The best condition for the sugarcane bagasse delignification process was 1% (w/v) sodium hydroxide, 1:10 solid-liquid ratio, at 100 °C, and 150 rpm for 1 h. The results from a 33-day batch anaerobic digestion experiment indicate that the production of biogas and methane yield were concurrent with the increasing C/N and co-substrate VS/inoculum VS ratios. The total biogas yields from C/N 20.0 with co-substrate VS/inoculum VS 0.06 and C/N 30.0 with co-substrate VS/inoculum VS 0.18 ratios were 2777.0 and 9268.0 mL, respectively, including a methane yield of 980.0 and 3009.3 mL, respectively. The biogas and methane yield from C/N 30.0 were higher than the biogas and methane yields from C/N 20.0 by 70.04 and 67.44%, respectively. The highest biogas and methane yields corresponded with the highest C/N with co-substrate VS/inoculum VS ratios (30.0 and 0.18), being 200.6 mL/g VS_removed and 65.1 mL CH₄/g VS_removed, respectively.